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The best place to start is the product documentation that can be found on the Exchange Server CD. Next, check out http://www.microsoft.com/exchange and http://www.microsoft.com/technet/exchange for white papers, deployment guides and so forth. Finally check out the Exchange Resource Kits that can be purchased from http://mspress.microsoft.com/. You didn't say which version of Exchange you are using but if you are interested in Exchange 2000, check out this book at http://www.amazon.com/exec/obidos/ASIN/0072127392/qid%3D991781735/sr%3D1-1/northwestnetw-20/103-9082892-3164616.
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